Dithiophosphamates are the sulphur containing ligands which have tendency to form complexes with Tungsten metal. The Multinuclear compounds of Tungsten have been synthesized and characterized by different methods. Physical and Analytical measurements like conductivity measurement, TLC Technique used to check the purity of synthesized compounds. Enzyme inhibition activity of compounds has been carried out by cup plate method results show that the enzyme activity of ligands has considerably increased in the form of their metal complexes. Biocidal studies of synthesized compounds against certain Bacterial and Fungal species has been carried out by serial dilution method to evaluate the MIC (Minimum inhibitory concentration) value on the basis of MIC value it is interpretated that metal complexes are most active as compared to ligand fragments