A series of new bidentate ligands are dithiocarbamates of 4-Amino anti-pyrene and 2-aminothiozole (AADTC, ATDTC) were prepared by new synthetic methods, as the sodium salt. In the reaction of Chloroauric acid and Ruthenium Chloride with aadtc and atdtc the corresponding complexes were prepared. The complexes was characterized by Elemental Analysis, IR, ESR, H 1NMR and TGA-DTA.