A synthesis of some new thiosemicarbazide like acetyl hexan thiosemicarbazide by condensation of cyclohexylmethylketone with thiosemicarbazide is carried out. And their metal complexes were synthesized by condensation of acetylhexan thosemiocarbazide and different transition metal chloride salt of Cu(II), Co(II), Ni(II),Cd(II),Zn(II),Hg(II) and Fe(III) their characterization are done by different analytical techniques, such as elemental analysis,FT-IR, ES-Mass .