Financial risks are the critical variables in forming enterprise’s financial crisis, the cyclical showing of which undecided by the will of people is an objective law. This paper divides financial risks into three types what are Financial Environment-adaptation Risk (FEAR), Financial Resource-allocation Risk (FRAR) and Financial Stakeholder-cooperation Risk (FSCR), which constitutes the three-dimensional financial risk system of chemical enterprise. Based on the literature review, this paper analyses the formation and conduction mechanism of three-dimensional financial risks. Next, it explores the identification principle of three-dimensional financial risks so as to give an efficient method. Then, it builds some matrix identification models for identifying three-dimensional financial risks of chemical enterprise. Furthermore, a case study is also given..