China's urbanization will influence the future world economic development. China's s urbanization rate is from 10.6% in1949 to 53.73% in 2013, and the research center of the experts predict that China's urbanization rate will reach 60% in 2020.The characteristic of China's urbanization is the coordinated development of four modernizations, which includes informatization, industrialization, urbanization and agricultural modernization. This paper analysis the agricultural industrialization and green supply chain of agricultural products based on the new urbanization of China. At last, some suggestions are put forward, that is we should pay attention to the green supply chain of agricultural products based on internet of things (IOT). IOT is aimed at enabling the interconnection and integration of the green supply chain which represents the trend of the green supply chain of agricultural products performance improvement of advanced technical platform networking, and leads the green supply chain of agricultural products revolution.