The preparation and characterization of a new research series of metal complex of Titanium (III) and Oxovanadium (IV). In which titanium (III) a Oxovanadium (IV) as a metal ion and p-chlorobenzylidene-2-aminothiazole as a ligand are studied. The complexes [C20H18N4S2O2.TiCl2] and [C20H16N4S2Cl2O.VOSO4] have been characterized by elemental analysis, infrared, electronic absorptional spectral and magnetic susceptibility measurements. An octahedral geometry is predicted for Ti (III) and VO (IV) complexes.